Highly active Pt@Au nanoparticles encapsulated in perfluorosulfonic acid for the reduction of oxygen.

نویسندگان

  • Niancai Cheng
  • Huaiguang Li
  • Guoqiang Li
  • Haifeng Lv
  • Shichun Mu
  • Xueliang Sun
  • Mu Pan
چکیده

The Pt@Au catalysts demonstrate remarkably high oxygen reduction reaction (ORR) activity compared with Pt/C catalysts. The ORR of Pt(2)@Au(1)/C and Pt(1)@Au(2)/C is 9.5 and 6.6 times that of Pt/C, respectively. This improvement is attributed to the electronic structure effect of the Au core on the Pt shell and introduction of PFSA.

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عنوان ژورنال:
  • Chemical communications

دوره 47 48  شماره 

صفحات  -

تاریخ انتشار 2011